Research progress on evolution characteristics of mechanical damage of reservoirs after CO2-water-rock interaction

doi:10.16265/j.cnki.issn1003-3033.2025.07.1636

Abstract

Abstract:

In order to reveal the water-rock coupling mechanism of CO₂ geological storage. This study employed literature research and theoretical analysis to introduce the experimental conditions and methods for CO₂-water-rock reactions, the physicochemical property changes of reservoirs after CO₂ action, the evolution of microstructure, and the deterioration characteristics of mechanical properties. Key issues regarding the multi-field coupling effects of CO₂-water-rock interactions were proposed, and the research progress on each key issue was summarized and analyzed. The results indicate that systematic research on the dissolution effects of CO₂ in different phases and under long-term dynamic conditions is lacking in CO₂ immersion tests. The experimental setups fail to accurately simulate the migration characteristics of CO₂ in real reservoirs. The mechanism governing the generation, transport, and adhesion of precipitates in CO₂-water-rock reactions remains unclear. This leads to limited research on the correlation between pore structure evolution and mechanical property degradation in reservoirs. Furthermore, the substantive relationship between reservoir microstructure and macroscopic mechanical parameters has not yet been established, which hinders the development of multi-scale damage evolution models. Additionally, current models for reservoir mechanical property degradation do not fully account for the multi-field coupling effects of thermal-hydrological-mechanical-chemical-damage interactions.

Key words: CO₂ geological storage, CO₂-water-rock, mechanical properties, damage evolution, microstructure

CLC Number:

X936

HAO Jianfeng, ZHANG Jiahao, SUN Weiji, LIANG Bing, QIN Bing, GUO Chunyu. Research progress on evolution characteristics of mechanical damage of reservoirs after CO₂-water-rock interaction[J]. China Safety Science Journal, 2025, 35(7): 141-150.

Figures/Tables 3

References 49

[1]	EYITAYO S, ARBAD N, OKERRE C, et al. Advancing geological storage of carbon dioxide (CO₂) with emerging technologies for climate change mitigation[J]. International Journal of Environmental Science and Technology, 2024, 22(6): 1-34.
[2]	罗凡, 蒋岳峰, 甘蓉, 等. 超临界二氧化碳流量测量方法研究[J]. 中国测试, 2024, 50(1): 62-68.
	LUO Fan, JANG Yuefeng, GAN Rong, et al. Study on supercritical carbon dioxide flux measurement method[J]. China Measurement & Test, 2024, 50(1): 62-68.
[3]	张烈辉, 张涛, 赵玉龙, 等. 二氧化碳-水-岩作用机理及微观模拟方法研究进展[J]. 石油勘探与开发, 2024, 51(1): 199-211. doi: 10.11698/PED.20230544
	ZHANG Liehui, ZHANG Tao, ZHAO Yulong, et al. Research progress on the mechanism of carbon dioxide-water-rock interaction and microscopic simulation methods[J]. Petroleum Exploration and Development, 2024, 51 (1): 199-211.
[4]	李秋和. 超临界CO₂作用下砂岩力学特性与渗透性试验研究[D]. 太原: 太原理工大学, 2021.
	LI Qiuhe. Experimental study on mechanical properties and permeability of sandstone under supercritical CO₂ action[D]. Taiyuan: Taiyuan University of Technology, 2021.
[5]	苏二磊. 超临界CO₂作用下烟煤结构响应及对力学和渗透特性的影响机理[D]. 重庆: 重庆大学, 2021.
	SU Erlei. Structural response of bituminous coal under supercritical CO₂ and its influence mechanism on mechanical and permeability characteristics[D]. Chongqing: Chongqing University, 2021.
[6]	LYU Qiao, LONG Xinping, RANJITH G P, et al. Unconventional gas: experimental study of the influence of subcritical carbon dioxide on the mechanical properties of black shale[J]. Energies, 2016, 9(7): DOI:10.3390/en9070516.
[7]	LYU Qiao, LONG Xinping, RANJITH P G, et al. Experimental investigation on the mechanical properties of a low-clay shale with different adsorption times in sub-/super-critical CO₂[J]. Energy, 2018, 147: 1288-1298.
[8]	安祺祎. 超临界二氧化碳对干热岩储层岩石动态溶蚀机理研究[D]. 济南: 山东大学, 2022.
	AN Qiyi. Study on the dynamic dissolution mechanism of supercritical carbon dioxide on hot dry rock reservoirs[D]. Ji'nan: Shandong University, 2022.
[9]	YIN Hong, ZHOU Junping, XIAN Xuefu, et al. Experimental study of the effects of sub- and super-critical CO₂ saturation on the mechanical characteristics of organic-rich shales[J]. Energy, 2017, 132: 84-95.
[10]	AMERI W A, ABDULRAHEEM A, MAHMOUD M, et al. Long-term effects of CO₂ sequestration on rock mechanical properties[J]. Journal of Energy Resources Technology, 2016, 138(1):DOI:10.1115/1.4032011.
[11]	FENG Gan, KANG Yong, SUN Zedong, et al. Effects of supercritical CO₂ adsorption on the mechanical characteristics and failure mechanisms of shale[J]. Energy, 2019, 173: 870-882.
[12]	SOON C C, JOON J S. Swelling and mechanical property change of shale and sandstone in supercritical CO₂[J]. Journal of Korean Society For Rock Mechanics, 2012, 22(4): 266-275.
[13]	ZOU Yushi, LI Sihai, MA Xinfang, et al. Effects of CO₂-brine-rock interaction on porosity/permeability and mechanical properties during supercritical-CO₂ fracturing in shale reservoirs[J]. Journal of Natural Gas Science and Engineering, 2018, 49: 157-168.
[14]	ZHANG Shuwen, XIAN Xuefu, ZHANG Junping, et al. Mechanical behaviour of Longmaxi black shale saturated with different fluids: an experimental study[J]. RSC Advances, 2017, 7: 42 946-42 955.
[15]	陈逸云, 冯涛, 喻红艳, 等. CO₂-水-页岩相互作用的研究现状及展望[J]. 广州化学, 2020, 45(2): 53-63.
	CHEN Yiyun, FENG Tao, YU Hongyan, et al. Research status and prospect of CO₂-water-shale interaction[J]. Guangzhou Chemical, 2020, 45(2): 53-63.
[16]	PAN Yi, HUI Dong, LUO Pingya, et al. Experimental investigation of the geochemical interactions between supercritical CO₂ and shale: implications for CO₂ storage in gas-bearing shale formations[J]. Energy & Fuels, 2018, 32(2): 1963-1978.
[17]	ILGEN A, AMAN M, ESPINOZA D, et al. Shale-brine-CO₂ interactions and the long-term stability of carbonate-rich shale caprock[J]. International Journal of Greenhouse Gas Control, 2018, 78: 244-253.
[18]	BANDO S, TAKEMURA F, NISHIO M, et al. Dissolution process of a spherical rising supercritical or liquid CO₂, droplet in water[J]. Greenhouse Gas Control Technologies, 2003, 2(1): 1511-1516.
[19]	DARWISH N, HILAL N. A simple model for the prediction of CO₂ solubility in H₂O-NaCl system at geological sequestration conditions[J]. Desalination, 2010, 260(1): 114-118.
[20]	肖娜, 李实, 林梅钦. CO₂-水-方解石相互作用后岩石表观形貌及渗透率变化特征[J]. 科学技术与工程, 2017, 17(24): 38-44.
	XIAO Na, LI Shi, LIN Meiqin. Characteristics of apparent morphology and permeability of rocks after CO₂-water-calcite interaction[J]. Science Technology and Engineering, 2017, 17(24): 38-44.
[21]	魏国. CO₂-水-岩反应对储层矿物转化及孔隙度的影响[D]. 北京: 中国石油大学(北京), 2023.
	WEI Guo. Effect of CO₂-water-rock reaction on mineral transformation and porosity of reservoir[D]. Beijing: China University of Petroleum(Beijing), 2023.
[22]	刘漪雯, 付美龙, 王长权, 等. CO₂驱不同注入方式对低渗透储层渗流能力的影响[J]. 油气地质与采收率, 2024, 31(2): 79-85.
	LIU Yiwen, FU Meilong, WANG Changquan, et al. Effect of different injection modes of CO₂ flooding on the seepage capacity of low permeability reservoirs[J]. Petroleum Geology and Recovery Efficiency, 2024, 31(2): 79-85.
[23]	李曜轩, 张艳, 王兴义, 等. 超临界二氧化碳压裂作用下页岩的力学特征与孔隙度变化规律研究[J]. 当代化工, 2020, 49(4): 572-576.
	LI Yaoxuan, ZHANG Yan, WANG Xingyi, et al. Study on the mechanical characteristics and porosity variation of shale under supercritical carbon dioxide fracturing[J]. Contemporary Chemical Industry, 2020, 49(4): 572-576.
[24]	杨术刚, 蔡明玉, 张坤峰, 等. CO₂-水-岩相互作用对CO₂地质封存体物性影响研究进展及展望[J]. 油气地质与采收率, 2023, 30(6): 80-91.
	YANG Shugang, CAI Mingyu, ZHANG Kunfeng, et al. Research progress and prospect of CO₂-water-rock interaction on petrophysical properties of CO2 geological sequestration[J]. Petroleum Geology and Recovery Efficiency, 2023, 30(6): 80-91.
[25]	PLUYMAKERS A, LIU J, KOHLER F, et al. A high resolution interferometric method to measure local swelling due to CO₂ exposure in coal and shale[J]. International Journal of Coal Geology, 2018, 187: 131-142.
[26]	AO Xiang, LU Yiyu, TANG Jiren, et al. Investigation on the physics structure and chemical properties of the shale treated by supercritical CO₂[J]. Journal of CO₂ Utilization, 2017, 20: 274-281.
[27]	YIN Hong, ZHOU Junping, JIANG Yongdong, et al. Physical and structural changes in shale associated with supercritical CO₂ exposure[J]. Fuel, 2016, 184: 289-303.
[28]	LI Ning, JIN Zhijun, ZHANG Shicheng, et al. Micro-mechanical properties of shale due to water/supercritical carbon dioxide-rock interaction[J]. Petroleum Exploration and Development Online, 2023, 50(4): 1001-1012.
[29]	白冰. 超临界二氧化碳对页岩力学性质影响的实验研究[D]. 青岛: 中国石油大学(华东), 2019.
	BAI Bing. Experimental study of the effect of supercritical carbon dioxide on the mechanical properties of shale[D]. Qingdao: China University of Petroleum(East China), 2019.
[30]	李一波, 陈耀旺, 赵金洲, 等. 超临界二氧化碳与页岩相互作用机制[J]. 石油与天然气地质, 2024, 45(4): 1180-1194.
	LI Yibo, CHEN Yaowang, ZHAO Jinzhou, et al. Interaction mechanism between supercritical carbon dioxide and shale[J]. Oil & Gas Geology, 2024, 45(4): 1180-1194.
[31]	郧嘉琳. 二氧化碳作用后致密砂岩力学性质变化特征研究[D]. 北京: 中国地质大学(北京), 2020.
	YUN Jialin. Study on the change characteristics of mechanical properties of tight sandstone after carbon dioxide action[D]. Beijing: China University of Geosciences(Beijing), 2020.
[32]	曾梦茹. 不同温度超临界CO₂条件下煤微观结构特征及改造机理研究[D]. 重庆: 重庆大学, 2020.
	ZENG Mengru. Study on the microstructure characteristics and transformation mechanism of coal under supercritical CO₂ conditions at different temperatures[D]. Chongqing: Chongqing University, 2020.
[33]	GUO Xing, NI Hongjian, LI Mukun, et al. Experimental study on the influence of supercritical carbon dioxide soaking pressure on the mechanical properties of shale[J]. Indian Geotechnical Journal, 2018, 48(2): 384-391.
[34]	ZHOU Zhe, SHENG Meiyu, GE Zhaolong, et al. Mechanical properties and failure characteristics of supercritical carbon dioxide soak in water-bearing coal rocks[J]. Energy, 2024, 286:DOI:10.1016/J.ENERGY.2023.129599.
[35]	黄应华. 超临界CO₂作用对页岩动静态力学性质影响研究[D]. 北京: 中国石油大学(北京), 2023.
	HUANG Yinghua. Study on the influence of supercritical CO₂ on dynamic and static mechanical properties of shale[D]. Beijing: China University of Petroleum(Beijing), 2023.
[36]	王奇生. 超临界二氧化碳对页岩物性影响的微观实验研究[D]. 北京: 中国石油大学(北京), 2022.
	WANG Qisheng. Microscopic experimental study of the effect of supercritical carbon dioxide on the physical properties of shale[D]. Beijing: China University of Petroleum(Beijing), 2022.
[37]	丁璐, 倪红坚. 超临界二氧化碳浸泡对页岩力学性能的影响[J]. 科学技术与工程, 2019, 19(30): 122-127.
	DING Lu, NI Hongjian. Effect of supercritical carbon dioxide immersion on mechanical properties of shale[J]. Science Technology and Engineering, 2019, 19(30): 122-127.
[38]	左罗, 仲冠宇, 蒋廷学, 等. 页岩微观结构及力学特征变化规律研究[J]. 西南石油大学学报:自然科学版, 2022, 44(5): 125-134.
	ZUO Luo, ZHONG Guanyu, JIANG Tingxue, et al. Study on the change law of shale microstructure and mechanical characteristics[J]. Journal of Southwest Petroleum University:Natural Science Edition, 2022, 44(5): 125-134.
[39]	田时锋, 周军平, 鲜学福, 等. 超临界CO₂作用下页岩抗拉强度的变化规律[J]. 煤炭学报, 2023, 48(7): 2728-2736.
	TIAN Shifeng, ZHOU Junping, XIAN Xuefu, et al. Variation of tensile strength of shale under supercritical CO₂[J]. Journal of China Coal Society, 2023, 48(7): 2728-2736.
[40]	汤积仁, 卢义玉, 陈钰婷, 等. 超临界CO₂作用下页岩力学特性损伤的试验研究[J]. 岩土力学, 2018, 39(3): 797-802.
	TANG Jiren, LU Yiyu, CHEN Yuting, et al. Experimental study on the damage of mechanical properties of shale under supercritical CO₂[J]. Rock and Soil Mechanics, 2018, 39(3): 797-802.
[41]	吴潇, 刘润昌. CO₂作用下碳酸盐岩物性及孔喉结构变化特征[J]. 油气藏评价与开发: 1-10.[2024-09-12]. http://kns.cnki.net/kcms/detail/32.1825.TE.20240911.2055.002.html.
	WU Xiao, LIU Runchang. Characteristics of carbonate rock physical properties and pore throat structure under CO₂ action[J]. Petroleum Reservoir Evaluation and Development: 1-10.[2024-09-12]. http://kns.cnki.net/kcms/detail/32.1825.TE.20240911.2055.002.html.
[42]	HOSSEIN S, REZA A K, MOHSEN M. Experimental investigation of the effects of oil asphaltene content on CO₂ foam stability in the presence of nanoparticles and sodium dodecyl sulfate[J]. Petroleum Exploration and Development, 2024, 51(1): 239-250.
[43]	王开喜. 静/动态压力的超临界CO₂及相关流体作用下页岩的力学特性研究[D]. 长沙: 中南大学, 2023.
	WANG Kaixi. Study on the mechanical properties of shale under supercritical CO₂ and related fluids under static/dynamic pressure[D]. Changsha: Central South University, 2023.
[44]	CHAE-SOON C, JINEON K, JAE-JOON S. Analysis of shale property changes after geochemical interaction under CO₂ sequestration conditions[J]. Energy, 2021, 214:DOI:10.1016/j.energy.2020.118933.
[45]	王海涛, 左罗, 郭印同, 等. 二氧化碳对页岩力学性质劣化规律的影响[J]. 科学技术与工程, 2021, 21 (29): 12 536-12 542.
	WANG Haitao, ZUO Luo, GUO Yintong, et al. Effect of carbon dioxide on the deterioration of shale mechanical properties[J]. Science Technology and Engineering, 2021, 21 (29): 12 536-12 542.
[46]	HAO Jianfeng, GUO Chunyu, SUN Weiji, et al. Study on the deterioration and damage evolution characteristics of mechanical properties of siltstone after supercritical CO₂ treatment[J]. Journal of CO₂ Utilization, 2024, 89:DOI:10.1016/J.JCOU.2024.102972.
[47]	刘力源, 马文成, 王卫东. 超临界CO₂吸附诱发煤力学性质劣化的双重损伤效应分析[J]. 山东科技大学学报: 自然科学版, 2020, 39(4): 79-86.
	LIU Liyuan, MA Wencheng, WANG Weidong. Analysis of the double damage effect of supercritical CO₂ adsorption induced deterioration of coal mechanical properties[J]. Journal of Shandong University of Science and Technology: Natural Science, 2020, 39(4): 79-86.
[48]	肖畅, 王开, 张小强, 等. 超临界CO₂作用后无烟煤力学损伤演化特性及机理[J]. 煤炭学报, 2022, 47(6): 2340-2351.
	XIAO Chang, WANG Kai, ZHANG Xiaoqiang, et al. Mechanical damage evolution characteristics and mechanism of anthracite after supercritical CO₂ action[J]. Journal of China Coal Society, 2022, 47(6): 2340-2351.
[49]	贾毅超, 杨栋, 黄旭东, 等. 超临界CO₂对无烟煤力学强度劣化机制及其微观结构演变特征[J]. 煤炭科学技术, 2024, 52(11): 323-336.
	JIA Yichao, YANG Dong, HUANG Xudong, et al. Mechanism of mechanical strength deterioration of anthracite by supercritical CO₂ and its microstructure evolution characteristics[J]. Coal Science and Technology, 2024, 52(11): 323-336.

测试内容	表征技术	关键参数
微观结构和力学性质^[9-10]	纳米CT技术	孔隙结构
	原子力显微镜	有机质的黏附力
	原子力显微镜	黏土的黏附力
	聚焦离子束显微镜	岩石层理定位
	超声波	弹性参数
	纳米压痕技术	微观力学性质
	核磁共振技术	微观结构
	表面物性测试技术	矿物元素及氧化物
	扫描电镜	矿物组分
	X射线荧光光谱仪
	X射线衍射仪
宏观力学性质^[11-12]	单轴压缩试验	弹性模量、泊松比、抗压强度
	三轴压缩试验	弹性模量、泊松比、抗压强度
	巴西劈裂试验	抗拉强度
宏观渗流特性^[13]	压汞试验	孔隙率
宏观渗流特性^[13]	多场耦合渗流试验	渗透率
溶液物性参数^[14]	离子检测盒	矿物离子浓度
溶液物性参数^[14]	pH计	溶液pH值

Research progress on evolution characteristics of mechanical damage of reservoirs after CO₂-water-rock interaction

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 3

References 49

Related Articles 8

Recommended Articles

Metrics

Comments

[1]	CHEN Kai, YU Mingsheng, LIU Long, WANG Shuai, ZHANG Zilong, WU Pengfei, ZHANG Haoran. Research on safety prevention and control technology of surrounding rock deformation in roadways based on jet grouting self-filling process [J]. China Safety Science Journal, 2025, 35(S1): 114-121.
[2]	LIN Sen, HAN Xiaohui, LI Gangqing, WANG Peng, ZHAO Cunjin, YANG Zhibin. Research on stress corrosion crack failure of MIG joints on aluminum alloy of high-speed trains [J]. China Safety Science Journal, 2022, 32(6): 115-122.
[3]	ZANG Zesheng, LI Zhonghui, NIU Yue, LIU Shuaijie, SONG Jingjing, ZHANG Quancong. Experimental study on mechanical properties of coal under different gas pressure [J]. China Safety Science Journal, 2021, 31(3): 90-95.
[4]	YANG Fan, LU Yi, LIU Yilun, SHI Shiliang, WANG Jinpeng, LI Songhui. Mechanical properties of elastic aerogel spherules for fire-fighting clothes filling [J]. China Safety Science Journal, 2020, 30(7): 180-185.
[5]	LI Xifan, XIONG Zuqiang, WANG Peng. Experimental study on improvement of mechanical properties of high-water filling materials in gob-side entry retaining [J]. China Safety Science Journal, 2020, 30(5): 95-100.
[6]	LU Yi, YANG Fan, SHI Shiliang, WU Fanghua, WANG Jinpeng. Heat resistance characteristics of aerogel spherules for thermal insulation lining in flame environment [J]. China Safety Science Journal, 2020, 30(5): 48-53.
[7]	SONG Xiaofeng, ZHI Youran, WANG Jinghong, WANG Zhirong. Analysis of post-fire properties and safety prediction of titanium equipment [J]. China Safety Science Journal, 2020, 30(12): 93-99.
[8]	ZHANG Shukun, WANG Shuda, WANG Laigui, SUN Qi. Stability study of roadway surrounding rock under influence of local weakening of structural plane [J]. China Safety Science Journal, 2018, 28(7): 116-121.