中国安全科学学报 ›› 2019, Vol. 29 ›› Issue (7): 51-57.doi: 10.16265/j.cnki.issn1003-3033.2019.07.009

• 安全工程技术科学 • 上一篇    下一篇

密闭球形空间内超细铝粉爆炸特性研究

屈姣1,2, 邓军1,2 教授, 王秋红1,2 副教授   

  1. 1 西安科技大学 安全科学与工程学院,陕西 西安 710054;
    2 西安科技大学 陕西省煤火灾害防治重点实验室,陕西 西安 710054
  • 收稿日期:2019-04-01 修回日期:2019-06-02 出版日期:2019-07-28
  • 作者简介:屈 姣 (1987—),女,陕西西安人,博士研究生,主要研究方向为粉尘爆炸及抑爆技术。E-mail:qujiao3131@163.com。
  • 基金资助:
    国家自然科学基金资助(51774232, 51804247);陕西省国际科技合作与交流计划项目(2016KW-070, 2018KW-035)。

Study on explosion characteristics of ultrafine aluminum powder in a closed spherical space

QU Jiao1,2, DENG Jun1,2, WANG Qiuhong1,2   

  1. 1 School of Safety Science and Engineering, Xi'an University of Science and Technology, Xi'an Shaanxi 710054, China;
    2 Shaanxi Key Laboratory of Coal Fire Hazard Prevention, Xi'an University of Science and Technology, Xi'an Shaanxi 710054, China
  • Received:2019-04-01 Revised:2019-06-02 Published:2019-07-28

摘要: 为探究超细铝粉在密闭球形空间内的爆炸危险性,采用20 L标准球形爆炸装置,研究不同试验条件下超细铝粉的爆炸特性,并分析粉尘质量浓度CD、氧气浓度CO2和粉尘平均粒径d50对爆炸特性参数(最大爆炸压力Pmax、最大压力上升速率(dP/dt)max、爆炸指数Kst) 的影响。结果表明:超细铝粉的爆炸下限质量浓度在50~80 g/m3范围内;随CD增大,100 nm铝粉Pmax先增大后减小,而 (dP/dt)maxKst也随之增大,且当CD为2 000 g/m3时,具有超强爆炸性;在贫氧环境下,随着CO2减小,超细铝粉氧化速率降低,释放热量减小,Pmax和(dP/dt)max均减小;对于800 nm,2 μm和10 μm等 3种粒径的铝粉,相同氧气浓度环境下,随着d50增大,铝粉比表面积减小,氧气扩散作用降低,Pmax和(dP/dt)max也随之减小。

关键词: 球形爆炸装置, 超细铝粉, 爆炸特性, 爆炸指数, 氧气浓度

Abstract: In order to understand the explosion hazard of ultrafine aluminum powder in a closed spherical space, its explosion characteristics under different test conditions were studied and the effects of dust concentration CD, oxygen concentration CO2 and average particle size of dust d50on explosion parameters (maximum explosion pressure Pmax, maximum pressure rise rate (dP/dt) max and explosion rate Kst) were analyzed by using a standard 20 L spherical explosive device. The results show that the minimum explosion concentration of ultrafine aluminum powder was in the range of 50-80 g/m3, for 100 nm aluminum powder, its Pmax increases first and then decreases while (dP/dt)max and Kst increase with the increase of CD, and it will be strongly explosive when the CD reaches 2 000 g/m3, in the oxygen-poor environment, with the decrease of CO2, the oxidation rate of ultrafine aluminum powder, the heat released and Pmax and (dP/dt)max will decrease, for aluminum powder with particle sizes of 800 nm, 2 μm and 10 μm, the powder's specific surface area will decrease, the diffusion of oxygen molecules will reduce, and Pmax and (dP/dt)max also will decrease with as the dust particle size of dust grows when the oxygen concentration maintains the same.

Key words: spherical explosive device, ultrafine aluminum powder, explosion characteristics, explosion index, oxygen concentration

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