一种早强膨胀延迟封孔材料制备及性能研究

doi:10.16265/j.cnki.issn1003-3033.2018.03.025

中国安全科学学报 ›› 2018, Vol. 28 ›› Issue (3): 144-148.doi: 10.16265/j.cnki.issn1003-3033.2018.03.025

一种早强膨胀延迟封孔材料制备及性能研究

马梦晓^1,2, 刘健^1,2 教授, 吉小利³ 副教授, 吴芬^1,2, 罗麒^1,2, 张超^1,2

1 安徽理工大学能源与安全学院, 安徽淮南 232001;
2 安徽理工大学煤炭高效开采省部共建教育部重点实验室, 安徽淮南 232001;
3 安徽理工大学化学工程学院, 安徽淮南 232001

收稿日期:2017-12-02 修回日期:2018-02-10 出版日期:2018-03-28 发布日期:2020-11-09
作者简介:马梦晓 (1992—),女,回族,安徽安庆人,硕士研究生,研究方向为安全管理。E-mail:15856695753@163.com。
基金资助:
国家自然基金面上项目资助(51674009);安徽省高校自然科学研究重点项目(KJ2016A1982016);国家级大学生创新训练项目(201610361014)。

Preparation and properties of a kind of accelerating early strength delayed expansion mine sealing material

MA Mengxiao^1,2, LIU Jian^1,2, JI Xiaoli ³, WU Fen^1,2, LUO Qi^1,2, ZHANG Chao^1,2

1 School of Energy and Safety, Anhui University of Science and Technology, Huainan Anhui 232001, China;
2 Key Laboratory of Mine Safety and High Efficient Mining Jointlybuilt by Province and Education Ministry, Anhui University of Science and Technology, Huainan Anhui 232001, China;
3 School of Chemical Engineering, Anhui University of Science and Technology, Huainan Anhui 232001, China

Received:2017-12-02 Revised:2018-02-10 Online:2018-03-28 Published:2020-11-09

摘要/Abstract

摘要： 针对矿井水泥封孔材料硬化过程体积收缩及加入膨胀剂导致强度下降的问题,基于硅酸盐水泥,以聚丙烯酰胺为囊壁,包覆铝粉形成膨胀剂微胶囊,与铝酸钠、氯化钠、硫酸钠、三乙醇胺、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)为主要成分的复合早强剂联合使用,制备一种可达到早期强度与膨胀要求的矿用封孔材料;通过膨胀性能、抗压强度等测试,利用X射线衍射(XRD)分析法与扫描电子显微镜(SEM)等手段,研究外加剂对水泥封孔材料性能的影响。研究表明:当氯化钠掺量(占水泥质量的百分比)为0.5%、硫酸钠0.5%、三乙醇胺0.05%、AMPS1%、铝酸钠1%、铝粉微胶囊0.1%,1天抗压强度达到4.2 MPa,3天抗压强度达到6.7 MPa,膨胀时间延迟4 h,膨胀率达到19.32%,可实现强度与膨胀协调发展。

关键词: 封孔材料, 铝粉, 微胶囊, 膨胀性, 抗压强度

Abstract: In view of that conventional mine cement sealing materials cause shrinkage and conventional expansion agents cause the decreasing strength in the hardening process, a kind of accelerating early strength delayed expansion mine sealing material was prepared. The components of the material are silicate cement, aluminum powder in microcapsules formed by polyacrylamide, water sodium aluminate, sodium chloride, sodium sulfate, triethanolamine, and 2-Acrylamido-2-methyl-1-propanesulfonic acid(AMPS). The influences of admixtures on the properties of the material in early strength and expansion were studied by means of X ray diffraction (XRD) analysis and scanning electron microscopy(SEM). The results show that the compressive strength of the material after hydration for 1 day reaches 4.2 MPa and 3 days reaches 6.7 MPa, the delay time of expansion is 4 h and the inflation rate reaches 19.32% when the mass ratio of sodium chloride to cement is 0.5% ,sodium sulfate 0.5%, triethanolamine 0.05%, AMPS 1%, sodium aluminate 1%, and aluminum type microcapsule 0.1%, which satisfys the need of strength and expansion.

Key words: sealing material, aluminium powder, microencapsulation, expansion rate, compressive strength

中图分类号:

X936

马梦晓, 刘健, 吉小利, 吴芬, 罗麒, 张超. 一种早强膨胀延迟封孔材料制备及性能研究[J]. 中国安全科学学报, 2018, 28(3): 144-148.

MA Mengxiao, LIU Jian, JI Xiaoli , WU Fen, LUO Qi, ZHANG Chao. Preparation and properties of a kind of accelerating early strength delayed expansion mine sealing material[J]. China Safety Science Journal, 2018, 28(3): 144-148.

参考文献

[1] 宋吴兵,林柏泉,郝志勇,等.瓦斯抽采钻孔新型高水材料封孔性能的研究与应用[J].煤炭工程,2015,47(9): 94-96.
SONG Wubing, LIN Baiquan, HAO Zhiyong, et al. Study and application of new high water material sealing property in gas drainage borehole[J].Coal Engineering,2015,47(9): 94-96.
[2] 郭孟志,张向阳,孙向锋,等.顺层抽放钻孔封孔工艺[J].煤炭科技,2012(3): 103-104.
[3] 孙文标,郭兵兵,张瑞林.氢氧化钠对瓦斯抽采钻孔新型材料性能的影响[J].中国安全科学学报,2016, 26(3): 98-102.
SUN Wenbiao,GUO Bingbing, ZHANG Ruilin. Effect of sodium hydroxide on the properties of new materials for gas extraction drilling [J].China Safety Science Joural, 2016,26(3): 98-102.
[4] 娄振,魏国营,张书进,等.煤层动态裂隙瓦斯抽采技术试验研究[J].中国安全科学学报,2016,26(10): 127-132.
LOU Zhen, WEI Guoying, ZHANG Shujin,et al.Experimental research on gas extraction technology of dynamic fracture of coal seam [J].China Safety science Joural, 2016,26 (10): 127-132.
[5] 房嘉明,赵业城.混凝土膨胀剂机理及应用现状浅谈[J].建筑工程技术与设计,2015(16):1 926.
[6] 陈志勇.铝粉膨胀剂水泥和微膨胀水泥的工程应用[J].科技信息,2007(13): 127-128.
[7] 王栋民,陈华辉,欧阳世翕.高强流态膨胀混凝土力学性能和膨胀行为[J].硅酸盐学报,2004,32(4): 454-459.
WANG Dongmin,CHEN Huahui, OUYANG Shixi. High strength superplasticized expansive concrete mechanical properties and swelling behavior[J].Journal of the Chinese Ceramic Society, 2004,32(4): 454-459.
[8] 刘永强.掺HCSA膨胀剂超高性能混凝土性能的研究[D].长沙:湖南大学,2014.
LIU Yongqiang.Research on performance on UHPC incorporating HCSA expansion agent[D].Changsha:Hunan University,2014.
[9] 孙诗兵,聂光临,姚晓丹,等. 膨胀剂对普通硅酸盐水泥砂浆性能的影响[J].混凝土,2014(9): 94-96.
SUN Shibing, NIE Guanglin, YAO Xiaodan,et al.Research on the influence of expansive agents on properties of ordinary Portland mortar[J].Concrete,2014(9): 94-96.
[10] 苗苗.胶凝材料组成和温度对补偿收缩混凝土变形性能的影响[D].北京:清华大学,2012.
MIAO Miao.Inflence of binding material composition and temperature on the deformation of shrinkage-compensating concrete[D].Beijing:Tsinghua University,2012.
[11] 宣章伟,王小婷,吴海龙.延迟型膨胀剂对水泥基封孔材料性能的影响研究[J].中国安全生产科学技术,2016,11(6): 115-119.
XUAN Zhangwei,WANG Xiaoting,WU Hailong,Study on influence of delayed expansive agent to performance of cement-based hole sealing materials[J].Journal of Safety Science and Technology,2016,11(6):115-119.
[12] 宋少民,贾博雅.膨胀剂对大掺量粉煤灰混凝土强度与碳化的影响[J].建筑技术,2012,43(8): 755-757.
SONG Shaomin,JIA Boya.Influence of expansion agent on strength and carbonization of high volume powdered coal ash concrete[J].Building Technology,2012,43(8): 755-757.
[13] LIU Junlong, MA Haiyang,LI Qiang,et al. Study on optimization of high performance concrete admixtures[J].Transactions of Nanjing University of Aeronautics & Astronautics,2011,28(2): 206-210
[14] GARTNER E M,KURTIS K E,MONTERIRO P J M.Proposed mechanism of C-S-H growth tested by soft X-ray microscopy[J].Cement and Concrete Research,2000,30(5): 817-822.
[15] DOUBBLE D D,HELLAWELL A,PERRY S J.The hydration of portland cement[J].Nature,1976,261(2250): 486-488.
[16] 罗麒,刘健,吉小利,等.两种复合早强剂对煤矿封孔水泥早强效果影响的研究[J].中国安全生产科学技术,2016,12(12): 69-73.
LUO Qi,LIU Jian,JI Xiaoli,et al.Study on influence to early strength performance of hole sealing cement used in coal mine by two kinds of compound early strength agents[J].Journal of Safety Science and Technology,2016,12(12): 69-73.
[17] 林付亿,郑远林.硫酸钠早强剂对预拌混凝土工作性和抗压强度的影响[J].混凝土技术,2007(5): 3-4.
[18] GB/T50080—2011,普通混凝土拌合物性能试验方法标准[S].
GB/T50080-2011,The standard for test method of performance on ordinary fresh concrete[S].
[19] GB/T50081—2002,普通混凝土力学性能试验方法标准[S].
GB/T50081-2002,The standard for test method of mechanical properties on ordinary concrete[S].
[20] 孙璐,张海峰.三乙醇胺-氯化钠早强效果研究[J].河南建材,2010(6): 30-31.
[21] 吴海龙,刘健,娄亚北,等.新型硫酸锂复合早强剂对煤矿封孔水泥早强效果的影响研究 [J].中国安全生产科学技术,2014,10(8): 34-38.
WU Hailong,LIU Jian,LOU Yabei,et al.Study on influence to early strength performance of hole sealing cement used in coal mine by new lithium sulfate compound early strength agent[J].Journal of Safety Science and Technology,2014,10(8): 34-38.

一种早强膨胀延迟封孔材料制备及性能研究

Preparation and properties of a kind of accelerating early strength delayed expansion mine sealing material

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 12

编辑推荐

Metrics

本文评价

[1]	罗振敏, 王登飞, 丁旭涵. 抑尘剂效果评价指标准确性分析^*[J]. 中国安全科学学报, 2022, 32(1): 195-200.
[2]	李西凡, 熊祖强, 王鹏. 高水巷旁充填材料力学性能改进试验研究[J]. 中国安全科学学报, 2020, 30(5): 95-100.
[3]	朱雯, 苏云, 陈若颖, 李俊, 田苗. 相变微胶囊涂层织物在热防护服中的应用[J]. 中国安全科学学报, 2020, 30(12): 180-185.
[4]	屈姣, 邓军, 王秋红. 密闭球形空间内超细铝粉爆炸特性研究[J]. 中国安全科学学报, 2019, 29(7): 51-57.
[5]	陈海燕, 姚庆国, 张延松, 刘浩, 张兴旭. 微米级铝粉最低着火温度和爆炸特性试验研究[J]. 中国安全科学学报, 2019, 29(11): 96-102.
[6]	孙文标, 郭兵兵, 卢前明. SDS对瓦斯预抽孔封孔材料性能的影响[J]. 中国安全科学学报, 2018, 28(7): 88-94.
[7]	唐文文, 陈先锋, 牛奕, 张洪铭, 代华明, 王玉杰. NH₄H₂PO₄和SiO₂粉体对铝粉火焰传播特性的影响[J]. 中国安全科学学报, 2017, 27(8): 44-49.
[8]	杨坚, 尹土兵, 刘科伟, 刘志祥, 陈冲. 全尾砂胶结充填体强度影响因素响应面法研究[J]. 中国安全科学学报, 2017, 27(12): 103-109.
[9]	雷伟刚, 毕海普讲师, 王凯全教授. 弯管内铝粉二次爆炸及抑爆试验研究^*[J]. 中国安全科学学报, 2017, 27(11): 43-48.
[10]	孙庆巍，朱涵，崔正龙. 粉煤灰-煤矸石基胶结充填材料制备与性能研究[J]. 中国安全科学学报, 2012, 22(11): 74-.
[11]	张一博，谭迎新. 激波诱导铝粉二次爆炸的试验研究[J]. 中国安全科学学报, 2012, 22(10): 61-.
[12]	秦涧，谭迎新，尉存娟. 水平管道内铝粉爆炸特性的试验研究[J]. 中国安全科学学报, 2011, 21(4): 66-.