中国安全科学学报 ›› 2018, Vol. 28 ›› Issue (2): 57-63.doi: 10.16265/j.cnki.issn1003-3033.2018.02.010

• 安全工程技术科学 • 上一篇    下一篇

基于F-K理论的大体积煤堆自燃特性试验研究

张晓明1,2 教授, 王永军2, 张河猛2, 佐佐木久郎3 教授   

  1. 1 辽宁工程技术大学 工程与环境研究所,辽宁 葫芦岛 125000;
    2 辽宁工程技术大学 矿业学院,辽宁 阜新 123000;
    3 九州大学 工学府,日本 福冈 819-0385
  • 收稿日期:2017-10-23 修回日期:2017-12-29 出版日期:2018-02-28 发布日期:2020-11-17
  • 作者简介:张晓明 (1962—),男,吉林长春人,教授,博士生导师,主要从事地下空间气象环境、煤层气和可燃冰开发、CO2地下封存、土木基础设施抗震性能评估、煤炭自然发火特性等方面的研究。E-mail: xmzhang7@126.com。
  • 基金资助:
    日本JSPS 重点资助项目(25303030)。

Experimental study on spontaneous combustion characteristics of big pile of coal based F-K theory

ZHANG Xiaoming1,2, WANG Yongjun2, ZHANG Hemeng1, SASAKI Kyuro3   

  1. 1 Institute of Engineering and Environment, Liaoning Technical University, Huludao Liaoning 125000, China;
    2 College of Mining Engineering, Liaoning Technical University, Fuxin Liaoning 123000, China;
    3 Faculty of Engineering, Kyushu University, Fukuoka 819-0395, Japan
  • Received:2017-10-23 Revised:2017-12-29 Online:2018-02-28 Published:2020-11-17

摘要: 为预测大体积低品质煤炭自然发火温度,采用恒温加热系统和气体检测分析系统,研究煤堆的自热特性。根据Frank-Kamenetskii 边界条件理论,并结合自然对流和临界自燃着火点研究方法,分析煤堆内部的温度变化、水分蒸发及能量转变情况,进而探讨环境温度、氧化气体和煤自燃倾向性的关系。结果表明:煤样水分含量是导致其自热升温曲线出现下降阶段的重要因素,煤堆内部不同位置其温度下降阶段持续的时间不同;自热反应所产生气体浓度随煤温的升高而增高;未燃状态下,氧化作用最强阶段位于温度上升初始段后期;自然对流和低温氧化导致煤堆体积缩减,环境温度越高体积缩减程度越大;煤样临界自燃着火点研究方法可有效应用于大体积煤堆自燃着火点预测。

关键词: 临界自燃着火点温度, Frank-Kamenetskii 边界条件理论, 自然对流, 水分蒸发, 环境温度, 气体检测

Abstract: For the shake of studying the spontaneous combustion temperature of upscale low rank coal piles, experiments were made by means of a constant temperature heating system and a gas detection and analysis system among others. Based on the Frank-Kamenetskii boundary condition theory and the critical self-ignition temperature analysis method, the internal temperature, effect of water evaporation and energy conversion of coal pile were described. Then, the relationships between ambient temperature, oxidizing gas and coal spontaneous combustion tendency were examined. The results show that the water content of coal pile is an important factor leading to the appearing of a decreasing stage in the self-heating curve, and the duration of temperature decreasing depends on the position of the measuring point in the coal pile, that there is a positive correlation between the concentrations of gases produced by the oxidation reaction and the coal temperature, that under the condition of non self-ignition, the strongest stage of oxidation is the later stage of temperature rising process, that both natural convection and low temperature oxidation result in the reduction of coal pile volume, that the higher the ambient temperature, the greater the reduction will be, and that the critical self-ignition temperature theory can be effectively applied to the prediction of large volume coal pile spontaneous combustion.

Key words: critical self-ignition temperature, Frank-Kamenetskii boundary theory, natural convection, water evaporation, environment temperature, gas detection

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