China Safety Science Journal ›› 2020, Vol. 30 ›› Issue (2): 60-65.doi: 10.16265/j.cnki.issn1003-3033.2020.02.010

• Safety engineering technology • Previous Articles     Next Articles

Influence of time factor on diffusion coefficient based on classical model

ZHANG Xianshang1,2,3   

  1. 1. State Key Laboratory of Gas Disaster Detecting, Preventing and Emergency Controlling, Chongqing 400037, China;
    2. Gas Center, Chongqing Research Institute, China Coal Technology and Engineering Group, Chongqing 400037, China;
    3. College of Architecture & Environment, Sichuan University, Chengdu Sichuan 610065, China
  • Received:2019-11-18 Revised:2020-01-20 Online:2020-02-28 Published:2021-01-25

Abstract: In order to study influence of time factor on fitting and calculation of diffusion coefficient, theoretical error during fitting process was analyzed based on classical diffusion model. Then, variation trends of diffusion coefficient and determination coefficient R2 over time were analyzed through conventional and fixed intercept linear methods with experimental data of gas diffusion dynamics in coal particles at different time periods and intervals. The results show that theoretical error of fitting decreases as diffusion time extends, and diffusion coefficient calculated by conventional fitting and fixed intercept fitting tends to be the same over time. However, it varies a lot with the increase of time period and interval and is affected by data at zero time.

Key words: gas diffusion coefficient, classical diffusion model, diffusion time, linear fitting, fixed intercept

CLC Number: