中国安全科学学报 ›› 2026, Vol. 36 ›› Issue (7): 92-102.doi: 10.16265/j.cnki.issn1003-3033.2026.07.1844

• 安全技术与工程 • 上一篇    下一篇

聚合物对活性剂溶液雾化黏附降尘性能的影响

周群1,2,3(), 秦波涛1,2,3,**(), 张婉琳3, 赵猛3, 白克东3, 王刚3   

  1. 1 中国矿业大学 煤矿瓦斯与火灾防治教育部重点实验室, 江苏 徐州 221116
    2 中国矿业大学 煤矿灾害防控全国重点实验室, 江苏 徐州 221116
    3 中国矿业大学 安全工程学院, 江苏 徐州 221116
  • 收稿日期:2026-02-02 修回日期:2026-04-10 出版日期:2026-07-28
  • 通信作者:
    **秦波涛(1977—),男,重庆人,博士,教授,主要从事矿井粉尘、热动力灾害防治方面的研究。E-mail:
  • 作者简介:

    周 群 (1990—),男,山东济宁人,博士,副教授,主要从事矿井粉尘防治、粉尘监测监控等方面的研究。E-mail:

  • 基金资助:
    中央高校基本科研业务费专项资金资助(2025QN1033)

Effects of polymers on atomization, adhesion and dust control performances of surfactant solutions

Zhou Qun1,2,3(), Qin Botao1,2,3,**(), Zhang Wanlin3, Zhao Meng3, Bai Kedong3, Wang Gang3   

  1. 1 Key Laboratory of Gas and Fire Control for Coal Mines, China University of Mining and Technology, Xuzhou Jiangsu 221116, China
    2 State Key Laboratory of Coal Mine Disaster Prevention and Control, China University of Mining and Technology, Xuzhou Jiangsu 221116, China
    3 School of Safety Engineering, China University of Mining and Technology, Xuzhou Jiangsu 221116, China
  • Received:2026-02-02 Revised:2026-04-10 Published:2026-07-28

摘要:

为改善喷雾对煤尘的降尘性能,用表面活性剂与聚合物协同增效的方法提高溶液润湿黏附粉尘能力。采用溶液静态润湿参数(表面张力、接触角、黏附力、黏度)、分子动力学模拟及雾化降尘试验系统研究聚合物对活性剂溶液雾化黏附降尘性能的协同改善效应,研发兼具润湿与黏附双重性能的喷雾降尘溶液。结果表明:单体表面活性剂在显著改善溶液润湿性能的同时黏附力大幅降低;添加小剂量聚合物后水溶液黏附力有较大幅度提升,但润湿性能不佳;在聚合物作用下活性剂溶液在保持其润湿性能变化不大的前提下,黏附性能显著增强;同时,在聚合物作用下煤-活性剂作用能明显增强,活性剂分子更易于吸附煤分子;此外,随着聚合物质量分数(0~0.15%)的增加,活性剂溶液雾滴粒径呈现出先缓慢增大后快速增加的变化趋势,同时降尘效率展现出先快速提升后趋于稳定的特征,其质量分数拐点均为0.05%;在活性剂与聚合物协同作用下,水溶液雾化降尘性能明显提升,且以0.03%表面活性剂O与0.05%聚合物B所制备的复合溶液具有良好的润湿及雾化黏附煤尘性能,降尘效率达到88%以上。

关键词: 聚合物, 表面活性剂, 煤尘, 溶液雾化, 协同增效, 润湿黏附性, 降尘性能

Abstract:

To improve the dust suppression performance of the spray on coal dust, the synergistic method among the surfactants and polymers was used to enhance the wetting adhesion property of the solution. The synergistic improvement effect of the polymer on the wetting and adhesion performance of the surfactant solution was studied by using the static wetting parameters of the solution (surface tension, contact angle, adhesion force, viscosity), molecular dynamics simulation and the atomization dust suppression test system, and a dust suppression solution with both wetting and adhesion properties was developed. The results show that the single surfactant significantly improves the wetting performance of the solution, while the adhesion force is greatly reduced. After adding a small dose of polymer, the adhesion of the aqueous solution is significantly improved, but the wetting performance is not good. Under the effect of the polymer, the adhesion performance of the surfactant solution is significantly enhanced while maintaining little change in its wetting performance. Under the influence of polymers, the interaction between coal and surfactants becomes significantly stronger, and the surfactant molecules are more easily able to adsorb onto the coal molecules. Furthermore, with the increase of the polymer mass fraction (0-0.15%), the droplet size of the surfactant solution shows a changing trend of first slowly increasing and then rapidly increasing. Meanwhile, the dust suppression efficiency shows a trend of first rapidly increasing and then tending to stabilize, and the inflection point of the mass fraction is all 0.05%. Under the synergistic effect between the surfactant and polymer, the dust suppression performance of the spray field is remarkably improved. Moreover, the compound solution prepared with 0.03% surfactant O and 0.05% polymer B has good wetting and atomization adhesion performance to coal dust, and the dust suppression efficiency reaches more than 88%.

Key words: polymer, surfactant, coal dust, solution atomization, synergistic effect, wetting adhesion property, dust control ability

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