矿用CMC/ZrCit/GDL防灭火凝胶特性研究

doi:10.16265/j.cnki.issn1003-3033.2020.01.018

中国安全科学学报 ›› 2020, Vol. 30 ›› Issue (1): 114-120.doi: 10.16265/j.cnki.issn1003-3033.2020.01.018

矿用CMC/ZrCit/GDL防灭火凝胶特性研究

董凯丽^1,2, 王俊峰^2,3 教授, 梁择文^1,2, 石琪⁴ 教授

1.太原理工大学安全与应急管理工程学院,山西太原 030024;
2.太原理工大学山西省矿井通风与火灾防治工程技术研究中心,山西太原 030024;
3.太原理工大学矿业工程学院,山西太原 030024;
4.太原理工大学化学化工学院,山西太原 030024

收稿日期:2019-10-15 修回日期:2019-12-05 出版日期:2020-01-28 发布日期:2021-01-22
作者简介:董凯丽 (1995—),女,山西临汾人,硕士研究生,研究方向为矿井火灾防灭火材料E-mail:1211891144@qq.com。
基金资助:
山西省自然科学基金资助(201801D121265)。

Characteristics of CMC/ZrCit/GDL fire extinguishing gel used for mines

DONG Kaili^1,2, WANG Junfeng^2,3, LIANG Zewen^1,2, SHI Qi⁴

1. School of Safety and Emergency Management Engineering, Taiyuan University of Technology, Taiyuan Shanxi 030024, China;
2. Shanxi Engineering Research Center for Mine Ventilation and Fire Prevention, Taiyuan University of Technology, Taiyuan Shanxi 030024, China;
3. College of Mining and Technology, Taiyuan University of Technology, Taiyuan Shanxi 030024, China;
4. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan Shanxi 030024, China

Received:2019-10-15 Revised:2019-12-05 Online:2020-01-28 Published:2021-01-22

摘要/Abstract

摘要： 为防治煤自燃,研制一种由羧甲基纤维素钠(CMC)、柠檬酸锆(ZrCit)和葡萄糖酸-δ-内酯(GDL)组成的新型矿井防灭火凝胶。首先试验测试不同配比凝胶的成胶时间和黏度,选出适合不同情况下煤矿防灭火的凝胶配比;然后采用程序升温试验和热重(TG)试验分析凝胶的阻化性能和对煤自燃失重放热的影响。结果表明:凝胶的加入对煤的自燃有一定抑制作用;凝胶渗透过程中成胶,粘结在煤体的表面和裂隙之间;相同加热时间下加热到180 ℃,水的失重率比32号凝胶高出30%左右,说明凝胶固水性强,热稳定性良好。灭火模拟试验说明使用凝胶灭火,煤体降温快且不易复燃。

关键词: 煤自燃, CMC/ZrCit/GDL凝胶, 阻化性能, 热稳定性, 灭火

Abstract: In order to prevent and control spontaneous combustion of coal, a new fire-suppression gel is developed for mines, which consists of sodium carboxymethylcellulose (CMC), zirconium citrate (ZrCit) and gluconic-δ-lactone (GDL). Firstly, gelation time and viscosity of gel at different ratios were tested, and suitable ratios for fire preventing and extinguishing in different situations were selected. Then, its resistance performance and effects on weight loss and heat release of coal were analyzed through programming temperature and thermogravimetric (TG) experiments. The results show that addition of gel suppresses spontaneous combustion of coal. Gelation occurs during penetration, and it is cemented to coal surface and fills up cracks. When being heated to 180 ℃ within same time, water losses about 30% weight more than No.32 gel, which indicates that gel has strong water retention and good thermal stability. It is demonstrated by fire extinguishing simulation experiments that using gel for extinguishing fire can cool temperature quickly and will not cause re-ignition easily.

Key words: coal spontaneous combustion, CMC/ZrCit/GDL gel, resistance performance, thermal stability, fire extinguishing

中图分类号:

X936

董凯丽, 王俊峰, 梁择文, 石琪. 矿用CMC/ZrCit/GDL防灭火凝胶特性研究[J]. 中国安全科学学报, 2020, 30(1): 114-120.

DONG Kaili, WANG Junfeng, LIANG Zewen, SHI Qi. Characteristics of CMC/ZrCit/GDL fire extinguishing gel used for mines[J]. China Safety Science Journal, 2020, 30(1): 114-120.

参考文献

[1] 林柏泉, 常建华, 翟成. 我国煤矿安全现状及应当采取的对策分析[J]. 中国安全科学学报, 2006, 16(5): 42-47.
LIN Baiquan,CHANG Jianhua,ZHAI Cheng. Analysis on coal mine safety situation in China and its countermeasures[J]. China Safety Science Journal, 2006, 16(5): 42-47.
[2] XIA Tongqiang, ZHOU Fubao, WANG Xinxin, et al. Controlling factors of symbiotic disaster between coal gas and spontaneous combustion in longwall mining gobs[J]. Fuel, 2016, 182: 86-96.
[3] 王开胜, 陆伟, 杜云峰, 等. 防治煤自燃塑性水玻璃凝胶研究[J]. 矿业安全与环保, 2016, 43(1): 8-11.
WANG Kaisheng, LU Wei, DU Yunfeng, et al. Study on plastic water glass gel for preventing coal spontaneous combustion [J]. Mining Safety and Environmental Protection, 2016, 43(1): 8-11.
[4] 朱红青, 胡超, 周全涛, 等. 泥浆泡沫性能及影响因素研究[J]. 矿业科学学报, 2019, 4(4): 343-348.
ZHU Hongqing, HU Chao, ZHOU Quantao, et al. Study on performances and influence factors of mud foam[J]. Journal of Mining Science and Technology, 2019, 4(4): 343-348.
[5] 杨胜强, 钟演, 夏春波, 等. 高水充填材料防灭火阻燃性能试验研究[J]. 煤炭科学技术, 2017, 45(1): 78-83.
YANG Shengqiang, ZHONG Yan, XIA Chunbo, et al. Experimental study on fire prevention and flame retardancy performances of high water backfill material [J]. Coal Science and Technology, 2017, 45(1): 78-83.
[6] 张钧祥, 宋维宾, 孙玉宁, 等. 新型高分子泡沫堵漏材料试验研究及工程应用[J]. 煤炭学报, 2018, 43(增1): 158-166.
ZHANG Junxiang, SONG Weibin, SUN Yuning, et al. Experimental study and application of new polymer foam plugging material [J]. Journal of China Coal Society, 2018, 43(S1): 158-166.
[7] HUANG Zhian, YAN Likai, ZHANG Yinghua, et al. Research on a new composite hydrogel inhibitor of tea polyphenols modified with polypropylene and mixed with halloysite nanotubes[J]. Fuel, 2019, 253: 527-539.
[8] TANG Yibo, WANG Huae. Development of a novel bentonite-acrylamide superabsorbent hydrogel for extinguishing gangue fire hazard[J]. Powder Technology, 2018, 323: 486-494.
[9] HU Shenggen, XUE Sheng. Gel fire suppressants for controlling underground heating[J]. Journal of Coal Science and Engineering (China), 2011, 17(3): 256-264.
[10] 周佩玲, 张英华, 黄志安, 等. 预防遗煤自燃的新型凝胶复合材料的研究[J]. 煤矿安全, 2016, 47(5): 34-37.
ZHOU Peiling, ZHANG Yinghua, HUANG Zhian, et al. Research on new gel composite materials to prevent spontaneous combustion of residual coal [J]. Safety in Coal Mines, 2016, 47 (5): 34-37.
[11] HU Shenggen, XU Sheng. Controlling heatings and gas leakage using innovative polymer gel-pilot-plant scale testing[R]. ACARP C22039 Final Report, CSIRO, Australia, 2005.
[12] 罗振敏, 邓军, 杨永斌,等. 煤矿井下灾区水凝胶密闭填充材料性能研究[J]. 中国矿业大学学报, 2007, 36(6): 748-751.
LUO Zhenmin, DENG Jun, YANG Yongbin, et al. Study on hydrogel material for sealing and filling in coal mine disaster zone [J]. Journal of China University of Mining and Technology, 2007, 36(6): 748-751.
[13] XU Yongliang, WANG Deming, WANG Lanyun, et al. Experimental research on inhibition performances of the sand-suspended colloid for coal spontaneous combustion[J]. Safety Science, 2012, 50(4): 822-827.
[14] 李昭水, 李帅龙, 李斌. 矿用新型防灭火凝胶的制备及性能研究[J]. 煤矿机械, 2018, 39(9): 46-48.
LI Zhaoshui, LI Shuailong, LI Bin. Study on preparation and performance of new type of fire extinguish gel for mine[J]. Coal Mine Machinery, 2018, 39(9): 46-48.
[15] CHENG Weimin, HU Xiangming, XIE Jun, et al. An intelligent gel designed to control the spontaneous combustion of coal fire prevention and extinguishing properties[J]. Fuel, 2017, 210: 826-835.
[16] 许越. 化学反应动力学[M]. 北京: 化学工业出版社, 2005: 25-70.

矿用CMC/ZrCit/GDL防灭火凝胶特性研究

Characteristics of CMC/ZrCit/GDL fire extinguishing gel used for mines

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