中国安全科学学报 ›› 2021, Vol. 31 ›› Issue (3): 41-46.doi: 10.16265/j.cnki.issn1003-3033.2021.03.006

• 安全工程技术 • 上一篇    下一篇

多孔矿物-聚磷酸铵对甲烷爆炸的协同抑制研究

袁必和1 副教授, 陶红吉1, 孙亚如1, 王连聪2, 陈先锋1 教授, 谭海**3 高级实验师   

  1. 1 武汉理工大学 安全科学与应急管理学院,湖北 武汉 430070;
    2 煤科集团沈阳研究院有限公司煤矿 安全技术国家重点实验室,辽宁 抚顺 113122;
    3 武汉理工大学 资源与环境工程学院,湖北 武汉 430070
  • 收稿日期:2020-12-14 修回日期:2021-02-01 出版日期:2021-03-28 发布日期:2021-12-20
  • 通讯作者: **谭 海(1970—),男,湖北通山人,本科,高级实验师,主要从事采矿工程、安全工程等方面的研究。E-mail:383394694@qq.com。
  • 作者简介:袁必和 (1988—),男,安徽庐江人,博士,副教授,主要从事安全功能材料、防火防爆技术等方面的研究。E-mail: yuanbh@whut.edu.cn。
  • 基金资助:
    国家重点研发计划项目(2017YFC0804705);国家自然科学基金资助(51703175);中央高校基本科研业务费资助项目(2020-zy-284);湖北省安全生产专项资金科技项目(KJZX202007004)。

Study on synergistic suppression of methane explosion by porous mineral materials-ammonium polyphosphate composite powder

YUAN Bihe1, TAO Hongji1, SUN Yaru1, WANG Liancong2, CHEN Xianfeng1, TAN Hai3   

  1. 1 School of Safety Science and Emergency Management, Wuhan University of Technology, Wuhan Hubei 430070, China;
    2 State Key Laboratory of Coal Mine Safety Technology, CCTEG Shenyang Research Institute, Fushun Liaoning 113122, China;
    3 School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan Hubei 430070, China
  • Received:2020-12-14 Revised:2021-02-01 Online:2021-03-28 Published:2021-12-20

摘要: 为探究新型多孔矿物(MTS)-聚磷酸铵(APP)复合粉体对甲烷-空气预混气爆炸的抑制效果,采用20 L球形爆炸装置开展多孔矿物、APP及其复合粉体在不同组成、不同添加浓度条件下的甲烷爆炸抑制试验,并使用热分析仪研究其热解行为。研究结果表明:当粉体添加量为0.100 g/L,多孔矿物与APP质量组成比为1∶3时,复合粉体对甲烷爆炸的协同抑制效果最显著,各爆炸参数均得到弱化;复合粉体对甲烷的协同抑爆机制包括物理及化学抑制,多孔矿物的复杂结构能增强其对自由基的捕获,多孔矿物和APP先后发生热分解反应可持续吸收热量,分解产物具有稀释、冷却及隔离效应,并能消耗燃烧反应中的自由基。

关键词: 多孔矿物(MTS), 聚磷酸铵(APP), 甲烷-空气预混气, 抑爆, 热稳定性

Abstract: In order to ascertain explosion suppression efficiency of a novel porous mineral material (Trade name: MTS)-APP powder inhibitor, a 20 L spherical explosion experimental apparatus was employed to study suppression effects of MTS, APP and their mixtures with different component proportions and added concentrations on methane-air explosion. Their pyrolysis behavior were evaluated by using a thermal analyzer. The results show that the synergistic inhibition effect of composite powder on methane explosion is most obvious when the addition of powder is 0.100 g/L and the ratio of porous mineral to APP is 1∶3 with the weakening of each explosion parameter. Synergistic explosion suppression mechanism of MTS-APP powder consists of physical and chemical inhibition performances. The porous structure endows MTS with labyrinth effect, which enhances free radicals trapping ability. The successive endothermic decomposition reactions of MTS and APP can persistently absorb heat. Moreover, the decomposition products have the effects of dilution, cooling and isolation, and can consume the free radicals in the combustion reaction.

Key words: porous mineral materials(MTS), ammonium polyphosphate (APP), premixed methane-air, explosion suppression, thermal stability

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