中国安全科学学报 ›› 2025, Vol. 35 ›› Issue (7): 48-56.doi: 10.16265/j.cnki.issn1003-3033.2025.07.1624

• 安全工程技术 • 上一篇    下一篇

钾盐粉体抑制瓦斯爆炸超压特性研究

贾进章1,2(), 田秀媛1,2,**()   

  1. 1 辽宁工程技术大学 安全科学与工程学院, 辽宁 阜新 123000
    2 辽宁工程技术大学 矿山热动力灾害与防治教育部重点试验室, 辽宁 葫芦岛 125105
  • 收稿日期:2025-03-01 修回日期:2025-05-07 出版日期:2025-07-28
  • 通信作者:
    ** 田秀媛(1997—),女,辽宁大连人,博士研究生,主要研究方向为瓦斯灾害防治。E-mail:
  • 作者简介:

    贾进章 (1974—),男,河北石家庄人,博士,教授,主要从事矿井智能通风与瓦斯防治、CO2封存与促抽煤层气等方面的研究。E-mail:

  • 基金资助:
    国家自然科学基金资助(52374203); 国家自然科学基金资助(52174183)

Study on characteristics of potassium salt powder in inhibiting gas explosion overpressure

JIA Jinzhang1,2(), TIAN Xiuyuan1,2,**()   

  1. 1 College of Safety Science and Engineering, Liaoning Technical University, Fuxin Liaoning 123000, China
    2 Key Laboratory of Mine Thermodynamic disasters and Control of Ministry of Education, Liaoning Technical University, Huludao Liaoning 125105, China
  • Received:2025-03-01 Revised:2025-05-07 Published:2025-07-28

摘要: 为防范矿井瓦斯爆炸事故,深入探究钾盐粉体的抑爆性能及其在管网中的作用特征,利用包含并联管路、分岔管路和角联管路的管网,开展在N2驱动下的KHCO3、K2C2O4和KH2PO4这3种钾盐粉体抑制瓦斯爆炸的试验,通过热重(TG)分析粉体的热解特性,结合超压变化监测,探究不同钾盐粉作用下的爆炸超压和超压衰减系数,并借助Chemkin-Pro模拟软件剖析抑爆机制。结果表明:3种粉体抑爆后冲击波压力叠加衰减过程消失,超压时程曲线呈单峰值特性,KHCO3粉体对爆炸超压峰值的抑制效果最佳,下降幅度达83.2%~88.9%,K2C2O4次之,KH2PO4相对较弱;斜角联支管4中的压力衰减程度较其他支管中更大;支管4和拐弯段能够借助自身结构特性提升超压衰减效果,是布设抑制剂的优选位置,KHCO3能最大程度利用这一结构特性增强抑爆效果;支线段冲击波超压衰减系数K2出现了小于1的情况,添加K2C2O4和KH2PO4粉体会加剧这一现象;KHCO3工况下自由基含量最低,抑爆效果最佳,其次是K2C2O4工况,最后是KH2PO4工况。

关键词: 钾盐粉体, 瓦斯爆炸, 爆炸超压, 超压衰减, 管网

Abstract:

To prevent and contain mine gas explosion accidents, the explosion suppression performance of potassium salt powders and their action laws in the pipe network were deeply explored. In a pipe network with parallel pipelines, branching pipelines, and angular connecting pipelines, an experimental study on the suppression of gas explosions by three potassium salt powders, namely KHCO3, K2C2O4, and KH2PO4, driven by N2, was carried out. The pyrolysis characteristics of the powders were studied through thermogravimetric(TG) analysis. By combining explosion experiments, the overpressure changes were monitored. The explosion overpressure and overpressure attenuation coefficient under the action of potassium salt powder were explored. Moreover, the explosion suppression mechanism was analyzed with the assistance of the Chemkin-Pro simulation software. The results indicate that after the explosion suppression by the three powders, the superposition and attenuation process of the shock wave pressure is eliminated, and the overpressure time-history curve exhibits a "single peak value" characteristic. Among them, the KHCO3 powder has the best suppression effect on the explosion overpressure peak value, with a decrease range of 83.2% - 88.9%. K2C2O4 ranks second, and KH2PO4 is relatively weaker. The pressure attenuation degree in the oblique angular connecting branch pipe 4 is greater than that in other branch pipes. Both the branch pipe 4 and the turning section can leverage their own structural characteristics to enhance the overpressure attenuation effect, and they are regarded as preferred locations for installing explosive inhibitors. KHCO3 is able to maximize the utilization of this structural characteristic to enhance the explosion suppression effect. Additionally, the shock wave overpressure attenuation coefficient K2 of the branch pipeline section shows a situation where it is less than 1.This phenomenon is found to be exacerbated by the addition of K2C2O4 and KH2PO4 powders. Through the analysis using the Chemkin-Pro simulation software, it is concluded that the free radical content under the KHCO3 working condition is the lowest, and the explosion suppression effect is the best, followed by the K2C2O4 working condition, and finally the KH2PO4 working condition.

Key words: potassium salt powder, gas explosion, explosion overpressure, overpressure attenuation, pipe network

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